Transcription

Safety Data SheetRevision Number: 001.3Issue date: 04/09/20181. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIERProduct identifier used on the label: Purex Liquid Laundry Detergent - After the RainRecommended use of the chemical and restrictions on use:Universal, No restrictions on use.Name, address and telephone number of the chemical manufacturer:Henkel CorporationOne Henkel WayRocky Hill, Connecticut 06067Telephone: For medical emergencies 1-833-359-6299 For transportation CHEMTREC: 1-800-424-9300Internet: www.henkel-northamerica.com2. HAZARDS IDENTIFICATIONThe hazards described in this Globally Harmonized System Safety Data Sheet (SDS) are not intended for consumers, and doesnot address consumer use of the product. For information regarding consumer applications of this product, refer to the productlabel.Classification of the substance or mixture in accordance with paragraph (d) of §1910.1200HAZARD CLASSSKIN IRRITATIONEYE IRRITATIONHAZARD CATEGORY22ASignal word, hazard statement(s), symbol(s) and precautionary statement(s) in accordance with paragraph (f) of §1910.1200Signal word:Hazard Statement(s):Causes skin irritation.Causes serious eye irritation.WARNINGSymbol(s):Precautionary zards not otherwiseclassified:Wash thoroughly after handling.Wear eye and face protection.Wear protective gloves.IF ON SKIN: Wash with plenty of water.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present andeasy to do. Continue rinsing.If skin irritation occurs: Get medical attention.If eye irritation persists: Get medical attention.Take off contaminated clothing.Not prescribedNot prescribedNone knownClassification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of theUnited Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).See Section 11 for additional toxicological information.3. COMPOSITION / INFORMATION ON INGREDIENTSPurex Liquid Laundry Detergent - After the RainRS Number: 381469Page 1 of 6

The following chemicals are classified as health hazards in accordance with paragraph (d) of § 1910.1200.CAS Number 3-23-07647-14-5Chemical Name*Alcohols, C12-18, 7-EO, sulfates, sodium saltsBenzenesulfonic acid, C10-13-alkyl derivs., sodium saltsSodium carbonateAlcohols, C12-18, 7EOSodium chlorideConcentration5 - 10 %1-5%1-5%1-5%1-5%*The specific chemical identity and/or exact percentage (concentration) of composition has been withheld because a trade secret is claimed in accordance with paragraph (i) of§1910.1200.4. FIRST AID MEASURESDescription of necessary measuresInhalation:Skin contact:Eye contact:Ingestion:Remove from exposure area to fresh air. Contact physician or local poison control center.Rinse affected area with large amounts of water until no evidence of product remains. Getmedical attention if irritation persists.Rinse eyes immediately with plenty of water, occasionally lifting upper and lower lids, until noevidence of product remains. Get medical attention if pain or irritation persist.Dilution by rinsing the mouth and giving a glass of water to drink is generally recommended.Contact physician or local poison control center.Most important symptoms and effects, both acute and delayedAfter eye contact: Moderate to strong irritation of the eyes (redness, swelling, burning, watering eyes). After skin contact: Temporaryirritation of the skin (redness, swelling, burning). After inhalation: Breathing high vapor concentrations may produce anestheticeffects, nausea, dizziness, headache. After ingestion: Ingestion may cause irritation of mouth, throat, digestive tract, diarrhea andvomiting.Indication of any immediate medical attention and special treatment neededAfter eye contact: Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. After skin contact: Rinse affected areawith large amounts of water until no evidence of product remains. After inhalation: Remove from exposure area to fresh air. Afteringestion: Administer immediately plenty of water. With ingestion of larger quantities (in adults one tablespoon) or in the case ofdiscomfort or pain seek immediate medical attention.5. FIRE FIGHTING MEASURESSuitable (and unsuitable) extinguishing mediaSuitable extinguishing media:Dry chemical, carbon dioxide, water spray or regular foam.Unsuitable extinguishing media:NoneSpecific hazards arising from the chemicalOxides of carbon and oxides of nitrogen.Special protective equipment and precautions for fire-fightersIn case of fire, wear a full-face positive-pressure self-contained breathing apparatus and protective suit. Shut off all ignition sourcesApply cooling water to sides of containers that are exposed to flames until well after fire is out. Avoid breathing vapors, keepupwind. Keep unnecessary personnel away.6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency proceduresWear skin, eye and respiratory protection as recommended in Section 8. Stop or reduce any leaks if it is safe to do so. Spillspresent a slipping hazard. Keep unnecessary personnel away. Ensure clean-up is conducted by trained personnel only. Make surearea is slip-free before re-opening to traffic.Environmental precautionsSmall or household quantities may be disposed in sewer or other liquid waste system. For larger quantities check with your localwater treatment plant.Purex Liquid Laundry Detergent - After the RainRS Number: 381469Page 2 of 6

Methods and materials for containment and cleaning upSMALL SPILLS: Contain and absorb with sand or other absorbent material and place into clean, dry containers for later disposal.Wash site of spillage thoroughly with water. LARGE SPILLS: Dike far ahead of spill to prevent further movement. Recover bypumping or by using a suitable absorbent material and place into containers for later disposal. Dispose in suitable waste container.7. HANDLING AND STORAGEPrecautions for safe handlingAvoid skin and eye contact. Do not ingest. Use with adequate ventilation. Avoid generating aerosols and mists. Keep the containersclosed when not in use.Conditions for safe storage, including any incompatibilitiesStore away from incompatible substances, excessive heat, flames, sparks or other ignition sources. Storage areas for largequantities (warehouse) should be well ventilated. Keep the containers tightly closed when not in use.8. EXPOSURE CONTROLS / PERSONAL PROTECTIONOSHA permissible exposure limit (PEL), American Conference of Governmental Industrial Hygienists (ACGIH) Threshold LimitValue (TLV), and any other exposure limit used or recommended by the chemical manufacturer, importer, or employer preparingthe safety data sheet, where available.Hazardous Component(s)Sodium carbonateSodium chlorideACGIH TLVOSHA PELAIHA te engineering controlsProvide local exhaust or general dilution ventilation to keep exposure to airborne contaminants below the permissible exposurelimits where mists or vapors may be generated.Individual protection measuresRespiratory:If respiratory protection is required, it must be based on the contamination levels found in theworkplace, must not exceed the working limits of the respirator and be jointly approved by theNational Institute for Occupational Safety and Health and the Mine Safety and HealthAdministration (NIOSH-MSHA).Eye:Splash-proof safety glasses are required to prevent eye contact where splashing of product mayoccur.Hand/Body:Chemical-resistant gloves are required where repeated or prolonged skin contact may occur.Protective clothing is required where repeated or prolonged skin contact may occur.9. PHYSICAL AND CHEMICAL PROPERTIESAppearance:Odor:Odor threshold:pH:Melting point/ range:Boiling point/range:Flash point:Evaporation rate:Flammable/Explosive limits - lower:Flammable/Explosive limits - upper:Vapor pressure:Vapor density:Solubility in water:Partition coefficient (n-octanol/water):Autoignition temperature:Decomposition temperature:Viscosity:VOC content:Specific gravity:liquidbluecitric, fruity, greenNot available.10.2 - 12.2 (25 C)Not available.Not available.Not available.Not available.Not available.Not available.Not available.Not available.SolubleNot available.Not available.Not available.300 - 700 mPa.sNot available.1.040 - 1.080 at 20 C (68 F)Purex Liquid Laundry Detergent - After the RainRS Number: 381469Page 3 of 6

10. STABILITY AND REACTIVITYReactivity:This product reacts with acids.Chemical stability:Stable under normal ambient temperature (70 F, 21 C) and pressure (1 atm).Possibility of hazardousreactions:Hazardous polymerization does not occur under normal temperatures and pressures.Conditions to avoid:Avoid storing in direct sunlight and avoid extremes of temperature.Incompatible materials:Strong oxidizers, acids.Hazardous decompositionproducts:Thermal decomposition products may include oxides of carbon.11. TOXICOLOGICAL INFORMATIONLikely routes of exposure including symptoms related to characteristicsInhalation:Skin contact:Eye contact:Ingestion:Physical/Chemical:Other relevant toxicityinformation:Unlikely to occur due to the physical properties of the product.Repeated or prolonged excessive exposure may cause irritation or dermatitis.This product may cause irritation with stinging, tearing, and redness.Ingestion of large quantities may cause gastrointestinal irritation with nausea, vomiting anddiarrhea.No physical/chemical hazards are anticipated for this product.This product is a laundry care product. The use of this product by consumers is safe undernormal and reasonable foreseen use.Numerical measures of toxicity, including delayed and immediate effectHazardous Component(s)Alcohols, C12-18, 7-EO, sulfates, sodiumsaltsBenzenesulfonic acid, C10-13-alkylderivs., sodium saltsSodium carbonateAlcohols, C12-18, 7EOSodium chlorideLD50s and LC50sImmediate and Delayed Health EffectsNoneNo DataNoneIrritantOral LD50 (RAT) 4,090 mg/kgInhalation LC50 (RAT, 2 h) 2.3 mg/lNoneOral LD50 (RAT) 3,000 mg/kgIrritant, SensoryIrritantIrritantCarcinogenicity informationHazardous Component(s)Alcohols, C12-18, 7-EO, sulfates, sodiumsaltsBenzenesulfonic acid, C10-13-alkylderivs., sodium saltsSodium carbonateAlcohols, C12-18, 7EOSodium chlorideCarcinogenicityMutagenicityToxicity for reproductionNTP CarcinogenIARC CarcinogenOSHA CarcinogenNoNoNoNoNoNoNoNoNoNoNoNoNoNoNoNone of the ingredients in this product are listed as carcinogens by the International Agency forResearch on Cancer (IARC), the National Toxicology Program (NTP) or the OccupationalSafety and Health Administration (OSHA).None of the ingredients in this product are known to cause mutagenicity.None of the ingredients in this product are known as reproductive, fetal, or developmentalhazards.Purex Liquid Laundry Detergent - After the RainRS Number: 381469Page 4 of 6

12. ECOLOGICAL INFORMATIONAquatic Toxicity:The following toxicity information is available for the hazardous ingredient(s) when used as technical grade and is provided asreference for the occupational settings. This product is anticipated to be safe for the environment at concentrations predicted inhousehold settings under normal use conditions.Toxicity to fish:The aquatic toxicity profile of this product has not been determined.Toxicity to aquatic invertebrates:The aquatic toxicity profile of this product has not been determined.Toxicity to algae:The aquatic toxicity profile of this product has not been determined.Persistence and degradabilityHazardous substancesResult valueCAS-No.Benzenesulfonic acid, C10- readily biodegradable13-alkyl derivs., sodiumsalts68411-30-3Alcohols, C12-18,readily biodegradableethoxylated68213-23-0Route ofapplicationaerobicSpeciesMethod85 %OECD Guideline 301 B (ReadyBiodegradability: CO2 EvolutionTest)aerobic79 %OECD Guideline 301 D (ReadyBiodegradability: Closed BottleTest)Bioaccumulative potentialThe bioaccumulation potential of this product has not been determined.Mobility in soilThe mobility of this product (in soil and water) has not been determined.13. DISPOSAL CONSIDERATIONSDescription of waste residues:Hazardous waste number:Not regulatedSafe handling and disposal methods:Recommended method of disposal:This product is not a RCRA hazardous waste and can be disposed of inaccordance with federal, state and local regulations.Disposal of uncleaned packages:Do not reuse this container.14. TRANSPORT INFORMATIONThe information in this section is for reference only and should not take the place of a shipping paper (bill of lading)specific to an order. Please note that the proper shipping classification may vary by packaging, properties, and mode oftransportation.U.S. Department of Transportation Ground (49 CFR)Proper shipping name:Not regulatedHazard class or division:NoneIdentification number:NonePacking group:NonePurex Liquid Laundry Detergent - After the RainRS Number: 381469Page 5 of 6

International Air Transportation (ICAO/IATA)Proper shipping name:Hazard class or division:Identification number:Packing group:Not regulatedNoneNoneNoneWater Transportation (IMO/IMDG)Proper shipping name:Hazard class or division:Identification number:Packing group:Not regulatedNoneNoneNone15. REGULATORY INFORMATIONOccupational safety and health act: Hazard Communication Standard, 29 CFR 1910.1200(g) Appendix D: The Occupational Safety andHealth Administration (OSHA) require that the Safety Data Sheets (SDSs) are readily accessible to employees for all hazardous chemicals in theworkplace. Since the use pattern and exposure in the workplace are generally not consistent with those experienced by consumers, this SDSmay contain health hazard information not relevant to consumer use.United States Regulatory InformationTSCA 8 (b) Inventory Status:All components are listed or are exempt from listing on the Toxic Substances Control ActInventor